湖南宝山矿床花岗岩类硫-铅同位素和流体包裹体研究及其成因意义   总被引：2，自引：0，他引：2  

丁腾  马东升  陆建军  章荣清  谢银财 《矿床地质》2016,35(4):663-676

宝山铜铅锌多金属矿床是湖南重要的铅锌生产基地。矿床内矽卡岩型铜(钼)矿化受侏罗纪花岗闪长斑岩的控制,而主要的铅锌矿体则产于远离岩体的碳酸盐地层中,且缺乏可靠的矿化年龄限制。为了查明宝山铅锌矿体与花岗闪长斑岩之间的成因关系,文章对宝山花岗岩类中浸染状黄铁矿的硫同位素和钾长石的铅同位素,以及铅锌矿石萤石脉石的流体包裹体进行了测试和研究,并与前人报道的铅锌硫化物矿石的硫、铅同位素进行了对比,尝试为宝山铅锌矿化的物质来源及成因提供依据。研究表明,花岗闪长斑岩中浸染状黄铁矿的δ34S值为+1.5‰~+3.5‰,与铅锌矿石硫化物(方铅矿、闪锌矿及黄铁矿)相一致;同时,花岗岩类中钾长石的铅同位素组成206Pb/204Pb、207Pb/204Pb和208Pb/204Pb分别为18.4789~18.7668、15.6835~15.7220和38.7903~39.1035,具有壳源的特征,且与铅锌矿石硫化物的铅同位素分布范围相吻合。宝山矿床的硫、铅同位素特征表明,花岗闪长斑岩应是铅锌矿化的主要硫源及金属来源。宝山矿床铅锌矿石萤石中的流体包裹体具有低温(130~150℃)、低盐度(8%)的特征,可能是岩浆热液演化到晚期的产物。结合已有的有关资料加以对比和分析,研究认为,宝山铅锌矿床的成矿物质应来源于花岗闪长岩的岩浆期后热液,在热液演化晚期迁移到远端地层中沉淀,形成了宝山的主要铅锌矿体。  相似文献   

河南嵩县店房金矿区花岗斑岩锆石U-Pb年龄、Hf同位素及岩石地球化学     

田永飞  叶会寿  李正远  毕珉烽  王鹏  原瑞杰  刘艺博 《地质学报》2016,90(8):1755-1777

华北陆块南缘外方山店房金矿区内出露后沟、水漉塘和店房钾长花岗斑岩体(脉),其与隐爆角砾岩筒及金矿化有密切的空间关系。为查明钾长花岗斑岩体的侵位时代、岩石成因和源区性质,本次开展了锆石U-Pb定年、锆石Hf同位素及岩石地球化学分析等研究。结果表明岩体具有高硅、高钾、富铝、低镁的特征,属钾玄岩系列Ⅰ型花岗岩,轻重稀土元素分馏明显,具有弱的Eu负异常,岩石富集Rb、K、Ba等,亏损Nb、Ta、Sr、P、Ti等元素。锆石具有核—边结构,其中锆石边SHRIMP U-Pb年龄142.6±2.1Ma(MSWD=1.4),_(εHf)(t)=-23.0~-13.8,两阶段模式年龄主要集中于2075~2652 Ma;锆石核LA-ICPMS U-Pb年龄可分为两组,即2169~2336Ma和1732~1881Ma,Hf同位素组成可分为两组,_(εHf)(t)分别集中于-13.1~-4.8和-4.5~3.7,模式年龄主要集中于2376~2805Ma。表明钾长花岗斑岩体形成于142.6±2.1Ma的早白垩世早期,岩浆可能由2169~2336Ma的古老下地壳新太古代太华群部分熔融而成,并有地幔组分参与,岩浆在上升或定位过程中捕获了1732~1881Ma熊耳群火山岩的锆石。结合区域构造背景认为,该岩体是早白垩世古太平洋板块向欧亚大陆俯冲致使华北陆块岩石圈减薄伸展而引起的岩浆活动的产物。  相似文献   

Petrogenesis and geodynamic evolution of the Kajan Neogene subvolcanic rocks,Nain, Central Iran     

《Chemie der Erde / Geochemistry》2016,76(4):567-578

Kajan subvolcanic rocks in the Urumieh–Dokhtar magmatic arc (UDMA), Central Iran, form a Late Miocene-Pliocene shallow-level intrusion. These subvolcanics correspond to a variety of intermediate and felsic rocks, comprising quartz diorite, quartz monzodiorite, tonalite and granite. These lithologies are medium-K calc-alkaline, with SiO₂ (wt.%) varying from 52% (wt.%) to 75 (wt.%). The major element chemical data also show that MgO, CaO, TiO₂, P₂O₅, MnO, Al₂O₃ and Fe₂O₃ define linear trends with negative slopes against SiO₂, whilst Na₂O and K₂O are positively correlated with silica. Contents of incompatible trace elements (e.g. Ba, Rb, Nb, La and Zr) become higher with increasing SiO₂, whereas Sr shows an opposite behaviour. Chondrite-normalized multi-element patterns show enrichment in LILE relative to HFSE and troughs in Nb, P and Ti. These observations are typical of subduction related magmas that formed in an active continental margin. The Kajan rocks show a strong affinity with calc-alkaline arc magmas, confirmed by REE fractionation (La_N/Yb_N = 4.5–6.4) with moderate HREE fractionation (Sm_N/Yb_N = 1.08–1.57). The negative Eu anomaly (Eu/Eu* <1), the low to moderate Sr content (< 400 ppm) and the Dy/Yb values reflect plagioclase and hornblende (+- clinopyroxene) fractionation from a calc-alkaline melt Whole–rock Sr and Nd isotope analyses show that the ⁸⁷Sr/⁸⁶Sr initial ratios vary from 0.704432 to 0.705989, and the ¹⁴³Nd/¹⁴⁴Nd initial ratios go from 0.512722 to 0.512813. All the studied samples have similar Sr-Nd isotopes, indicating an origin from a similar source, with granite samples that has more radiogenic Sr and low radiogenic Nd isotopes, suggesting a minor interaction with upper crust during magma ascent. The Kajan subvolcanic rocks plot within the depleted mantle quadrant of the conventional Sr-Nd isotope diagram, a compositional region corresponding to mantle-derived igneous rocks.  相似文献   

Iodine budget in surface waters from Atacama: Natural and anthropogenic iodine sources revealed by halogen geochemistry and iodine-129 isotopes     

《Applied Geochemistry》2016

Iodine enrichment in the Atacama Desert of northern Chile is widespread and varies significantly between reservoirs, including nitrate-rich “caliche” soils, supergene Cu deposits and marine sedimentary rocks. Recent studies have suggested that groundwater has played a key role in the remobilization, transport and deposition of iodine in Atacama over scales of millions-of-years. However, and considering that natural waters are also anomalously enriched in iodine in the region, the relative source contributions of iodine in the waters and its extent of mixing remain unconstrained. In this study we provide new halogen data and isotopic ratios of iodine (¹²⁹I/I) in shallow seawater, rivers, salt lakes, cold and thermal spring water, rainwater and groundwater that help to constrain the relative influence of meteoric, marine and crustal sources in the Atacama waters. Iodine concentrations in surface and ground waters range between 0.35 μM and 26 μM in the Tarapacá region and between 0.25 μM and 48 μM in the Antofagasta region, and show strong enrichment when compared with seawater concentrations (I = ∼0.4 μM). In contrast, no bromine enrichment is detected (1.3–45.7 μM for Tarapacá and 1.7–87.4 μM for Antofagasta) relative to seawater (Br = ∼600 μM). These data, coupled to the high I/Cl and low Br/Cl ratios are indicative of an organic-rich sedimentary source (related with an “initial” fluid) that interacted with meteoric water to produce a mixed fluid, and preclude an exclusively seawater origin for iodine in Atacama natural waters. Iodine isotopic ratios (¹²⁹I/I) are consistent with halogen chemistry and confirm that most of the iodine present in natural waters derives from a deep initial fluid source (i.e., groundwater which has interacted with Jurassic marine basement), with variable influence of at least one atmospheric or meteoric source. Samples with the lowest isotopic ratios (¹²⁹I/I from ∼215 to ∼1000 × 10⁻¹⁵) strongly suggest mixing between the groundwater and iodine storage in organic-rich rocks (with variable influence of volcanic fluids) and pre-anthropogenic meteoric water, while samples with higher values (∼2000–93,700 × 10⁻¹⁵) indicate the input of anthropogenic meteoric fluid. Taking into account the geological, hydrologic and climatic features of the Atacama region, we propose that the mean contribution of anthropogenic ¹²⁹I is associated with ¹²⁹I releases during nuclear weapon tests carried out in the central Pacific Ocean until the mid 1990's (¹²⁹I/I = ∼12,000 × 10⁻¹⁵). This source reflects rapid redistribution of this radioisotope on a global scale. Our results support the notion of a long-lived continental iodine cycle in the hyperarid margin of western South America, which is driven by local hydrological and climate conditions, and confirm that groundwater was a key agent for iodine remobilization and formation of the extensive iodine-rich soils of Atacama.  相似文献   

Geochemistry of Paraná-Etendeka basalts from Misiones,Argentina: Some new insights into the petrogenesis of high-Ti continental flood basalts     

《Journal of South American Earth Sciences》2016

The Early Cretaceous (∼135–131 Ma) Paraná-Etendeka continental flood basalts, preserved in bulk in the Paraná basin of southern Brazil and vicinity, have been divided into low-Ti and high-Ti types that govern the southern and northern halves of the basin, respectively. We have examined a new sample set from the southern margin of the northern high-Ti segment of Paraná basalts in Misiones, northeastern Argentina. These basalts are strongly to moderately enriched in TiO₂ (2–4 wt.%), have relatively high Ti/Y (300–500), low MgO (3.5–6.5 wt.%), and high Fe (FeO(tot) 12–14 wt.%) and belong to the Pitanga and Paranapanema magma types of Peate et al. (1992). Nd and Sr isotope compositions are quite unvarying with ε_Nd (at 133 Ma) values of −4.6 to −3.6 and initial ⁸⁷Sr/⁸⁶Sr of 0.7054–0.7059 and show no variation with fractionation. Compared to high-Ti lavas in the central and northern parts of the Paraná high-Ti basalt segment, the lavas from Misiones are similar to those in the northeastern magin of the basin but less radiogenic in initial Nd isotope composition than those in the central part. This variation probably reflects mixed EM1-EM2 source components in the sublithospheric mantle. A polybaric melt model of a sublithospheric mantle source at the garnet lherzolite-spinel lherzolite transition is compatible with the observed Ti budget of the Pitanga and Paranapanema lavas, regardless of the Nd isotope composition of their purported source.  相似文献   

大湖塘矿集区燕山成矿阶段矿床成矿系列研究及找矿问题探讨          下载免费PDF全文

王西荣  潘家永  李绍侠  王佳鑫 《地质找矿论丛》2016,31(2):206-212

大湖塘矿集区位于赣西北九岭成矿带西北部位,区内燕山期岩浆岩侵入活动及成矿作用强烈。大湖塘燕山期岩浆岩形成时间分布在130.3 Ma~151.4 Ma之间,可划分为三次侵入:130.3 Ma~134.3 Ma、140.4 Ma~144.4 Ma、146.4 Ma~151.4 Ma;在144.4 Ma~146.4 Ma之间,岩浆活动处于休宁阶段。区内燕山期岩浆岩与矿床在形成时间上十分接近,空间关系上相互依存,并显示特定的分布格局。根据区内矿床的分布特点、产出位置、成矿时间、燕山期花岗岩与矿床的相关性等特征,可将大湖塘矿集区由北向南依次划分为W、Mo—W、Mo、Cu、Pb、Zn—Cu、Pb、Zn、Au、Ag三个成矿系列,并提出了"北钨南铜"的找矿观点。区内双桥山群与成矿,燕山期岩浆岩的起源,矿床等间距分布,以及重力勘探方面的研究应加强。  相似文献   

西藏冈底斯中段桑桑花岗质岩体锆石U-Pb年龄与Hf同位素组成及其对岩石成因和构造演化的制约          下载免费PDF全文

王睿强  邱检生  喻思斌  赵姣龙 《高校地质学报》2016,22(1):81

以西藏冈底斯中段西侧桑桑花岗质岩体为对象,进行了系统的年代学、元素地球化学和锆石Hf同位素组成研究,据此阐明了岩体成因,并探讨了其构造意义。锆石LA-ICP-MS U-Pb定年表明,桑桑花岗质岩体的成岩年龄为49~54 Ma。化学组成上,岩体具有亚碱、准铝、贫磷的特征(A/NKC1.10,P_2O_50.20%),属钙碱性I型花岗岩类。岩体富Cs、Rb、Ba、Th、U、K、Pb和轻稀土,贫Nb、Ta、P与Ti,表现出弧岩浆岩的地球化学特征。岩体的锆石εHf(t)值变化较大,散布于正值与负值之间(=-4.24~+5.49),指示其形成存在不同来源物质的贡献。综合分析表明,桑桑花岗质岩体起源于初生地壳的部分熔融,但在成岩过程中有古老地壳组分的参与。结合区域地质背景,笔者认为这一古老地壳组分最可能来自印亚碰撞过程中俯冲下插的印度地壳,由此说明印度-欧亚大陆碰撞的起始时间应早于54 Ma。  相似文献   

湘南—桂东北地区寒武—奥陶纪沉积岩碎屑锆石U-Pb年代学特征及其地质意义   总被引：1，自引：0，他引：1       下载免费PDF全文

张雄  曾佐勋  刘伟  潘黎黎  杨宝忠  刘建雄  魏运许  贺赤诚  李绍凡 《中国地质》2016,(1):153-173

本文利用LA-ICP-MS分析技术,对湘南—桂东北地区寒武纪和奥陶纪沉积岩进行了碎屑锆石U-Pb年代学研究。获得有效年龄数据239组,年龄值变化范围较大(3146~474 Ma),主要集中分布于2633~2473 Ma(峰值2500Ma),1880~1521 Ma(峰值1650 Ma),1146~911 Ma(峰值970 Ma),896~720 Ma(峰值800 Ma)和682~474 Ma(峰值520 Ma)5个时间段。4件样品均记录了古太古代—中太古代年龄信息,同时以1146~911 Ma和896~720 Ma两个时间段年龄最集中,反映全球Grenville造山事件和全球Rodinia超大陆裂解事件对研究区影响显著。此外,本次还获得大量泛非期(520 Ma左右)锆石年龄,认为全球泛非事件对华夏地块及其邻区影响显著,反映华夏地块与冈瓦纳大陆可能有一定亲缘性。结合前人资料,认为研究区位于华夏地块和扬子地块西南段碰撞拼合带,研究区地层同时接受两地块物质沉积,物源主要来自华夏地块。  相似文献   

新疆白杨河铍铀矿床萤石Sm-Nd和沥青铀矿U-Pb年代学及其地质意义   总被引：3，自引：2，他引：1  

衣龙升  范宏瑞  翟明国  李月湘  马汉峰  田建吉  修晓茜 《岩石学报》2016,32(7):2099-2110

白杨河矿床是我国类型独特的一个特大型铍、铀多金属矿床,铍矿物主要确定为羟硅铍石,铀矿物主要发现沥青铀矿和次生的硅钙铀矿以及少量的铌铀矿,伴生矿物主要是萤石。为恢复铀和铍的成矿过程,划分成矿阶段,本次工作通过系统采集钻孔中的萤石样品,进行了Sm-Nd同位素测年研究,获得了三组等时线年龄,分别为291±16Ma、265±33Ma和207±37Ma,代表了成矿前、成矿期和成矿后萤石的形成;采集中心工地、新西工地和九号工地平巷内的沥青铀矿样品,进行了UPb同位素测年研究,获得了~(206)Pb/~(238)U表观年龄237.8±3.3Ma、224±3.1Ma、197.8±2.8Ma、97.8±1.4Ma和30.0±0.4Ma,利用U-Pb表观年龄将铀矿化划分为四个阶段:中三叠世、晚三叠-早侏罗世、晚白垩世和古近纪中期。因此,白杨河矿床具有铍早铀晚的成矿特点,铀成矿经历了四个阶段。  相似文献   

湘南荷花坪锡多金属矿床成矿年代研究   总被引：1，自引：1，他引：0  

蔡明海  张文兵  彭振安  刘虎  郭腾飞  谭泽模  唐龙飞 《岩石学报》2016,32(7):2111-2123

荷花坪锡多金属矿床是本世纪初在南岭中段湘南地区新发现的一个大型矿床,区内的锡多金属矿化产在王仙岭岩体东南内、外接触带,已发现有Ⅰ、Ⅱ、Ⅲ和Ⅳ号4个主要锡多金属矿体。其中,Ⅰ、Ⅱ和Ⅳ号矿体由早期矽卡岩型和晚期蚀变碎裂岩型矿石组成,Ⅲ号矿体则由独立产出的蚀变碎裂岩型矿石组成,且包含有部分碎裂花岗斑岩。以往研究已对Ⅳ号矿体中的矽卡岩型矿石和Ⅲ号矿体中含矿斑岩脉分别采用辉钼矿Re-Os法和锆石SHRIMP U-Pb法进行了测年,获得的年龄分别为224.0±1.9Ma和142±2Ma。本文补充了晚期蚀变碎裂岩型矿石的~(40)Ar/~(39)Ar测年,结果显示,Ⅱ号矿体中蚀变碎裂岩型矿石白云母样品和石英样品的坪年龄分别为151.88±1.58Ma和155.39±7.04Ma;Ⅳ号矿体中蚀变碎裂岩型矿石石英样品的坪年龄为156.94±1.64Ma。结合前人研究资料综合分析,认为荷花坪矿区存在印支晚期(224Ma)、燕山早期(151~156Ma)和燕山晚期(142Ma)三期成矿作用,分别与区内印支期中粗粒含电气石黑云母花岗岩、燕山早期中粗粒黑云母花岗岩和燕山晚期花岗斑岩脉有关,不同期成岩、成矿作用的构造环境均为岩石圈的拉张伸展。湘南地区印支期(205~224Ma)基性岩浆活动及荷花坪矿床印支期成岩、成矿过程中均有幔源物质的参与,它们共同指示南岭地区中生代构造体制的转换或岩石圈伸展减薄可能始于印支主期(230~244Ma)之后的224Ma左右,即晚三叠世。  相似文献